Halloysite Nanotube-Enhanced Polyacrylonitrile Ultrafiltration Membranes: Fabrication, Characterization, and Performance Evaluation.

This research focuses on the production and characterization of pristine polyacrylonitrile (PAN) as well as halloysite nanotube (HNT)-doped PAN ultrafiltration (UF) membranes via the phase inversion technique. Membranes containing 0.1, 0.5, and 1% wt HNT in 16% wt PAN are fabricated, and their chemical compositions are examined using Fourier transform infrared (FTIR) spectroscopy. Scanning electron microscopy (SEM) is utilized to characterize the membranes' surface and cross-sectional morphologies. Atomic force microscopy (AFM) is employed to assess the roughness of the PAN/HNT membrane. Thermal characterization is conducted using thermal gravimetric analysis (TGA) and differential thermal analysis (DTA), while contact angle and water content measurements reveal the hydrophilic/hydrophobic properties. The pure water flux (PWF) performance of the porous UF water filtration membranes is evaluated at 3 bar, with porosity and mean pore size calculations. The iron (Fe), manganese (Mn), and total organic carbon (TOC) removal efficiencies of PAN/HNT membranes from dam water are examined, and the surfaces of fouled membranes are investigated by using SEM post-treatment. Mechanical characterization encompasses tensile testing, the Mori-Tanaka homogenization approach, and finite element analysis. The findings offer valuable insights into the impact of HNT doping on PAN membrane characteristics and performance, which will inform future membrane development initiatives.

A review of microplastic removal from water and wastewater by membrane technologies.

Microplastics (MPs) cannot be completely removed from water/wastewater in conventional wastewater treatment plants (WWTPs) and drinking water treatment plants (DWTPs). According to the literature analysis, membrane technologies, one of the advanced treatment technologies, are the most effective and promising technologies for MP removal from water and wastewater. In this paper, firstly, the properties of MPs commonly present in WWTPs/DWTPs and the MP removal efficiency of WWTPs/DWTPs are briefly reviewed. In addition, research studies on MP removal from water/wastewater by microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), reverse osmosis (RO), and membrane bioreactors (MBRs) are reviewed. In the next section, membrane filtration is compared with other methods used for MP removal from water/wastewater, and the advantages/disadvantages of the removal methods are discussed. Moreover, the problem of membrane fouling with MPs during filtration and the potential for MP release from polymeric membrane structure to water/wastewater are discussed. Finally, based on the studies in the literature, the current status and research deficiencies of MP removal by membrane technologies are identified, and recommendations are made for further studies.

Abundance and characteristics of microplastics in drinking water treatment plants, distribution systems, water from refill kiosks, tap waters and bottled waters.

Limited research studies have revealed the presence of microplastics (MPs) of different polymer types, shapes, and sizes in drinking water sources, influents of drinking water treatment plants (DWTPs), effluents of DWTPs, tap water, and bottled water. Reviewing the available information on MP pollution in waters, which is becoming more worrying in correlation with the increasing plastic production in the world every year, is noteworthy for understanding the current situation, identifying the deficiencies in the studies, and taking the necessary measures for public health as soon as possible. Therefore, this paper, in which the abundance, characteristics, and removal efficiencies of MPs in the processes from raw water to tap water and/or bottled water are reviewed is a guide for dealing with MP pollution in drinking water. In this paper, firstly, the sources of MPs in raw waters are briefly reviewed. In addition, the abundance, and characteristics (polymer type, shape, and size) of MPs in influents and effluents of DWTPs in different countries are reviewed and the effects of treatment stages (coagulation, flocculation, sedimentation, sand filtration, disinfection, and membrane filtration) of DWTPs on MP removal efficiency and the factors that are effective in removal are discussed. Moreover, studies on the factors affecting MP release from drinking water distribution systems (DWDSs) to treated water and the abundance and characteristics of MPs in tap water, bottled water and water from refill kiosks are reviewed. Finally, the deficiencies in the studies dealing with MPs in drinking water are identified and recommendations for future studies are presented.

Microplastics in wastewater treatment plants: Sources, properties, removal efficiency, removal mechanisms, and interactions with pollutants.

Since wastewater treatment plants (WWTPs) cannot completely remove microplastics (MPs) from wastewater, WWTPs are responsible for the release of millions of MPs into the environment even in 1 day. Therefore, knowing the sources, properties, removal efficiencies and removal mechanisms of MPs in WWTPs is of great importance for the management of MPs. In this paper, firstly the sources of MPs in WWTPs and the quantities and properties (polymer type, shape, size, and color) of MPs in influents, effluents, and sludges of WWTPs are presented. Following this, the MP removal efficiency of different treatment units (primary settling, flotation, biological treatment, secondary settling, filtration-based treatment technologies, and coagulation) in WWTPs is discussed. In the next section, details about MP removal mechanisms in critical treatment units (settling and flotation tanks, bioreactors, sand filters, membrane filters, and coagulation units) in WWTPs are given. In the last section, the mechanisms and factors that are effective in adsorbing organic-inorganic pollutants in wastewater to MPs are presented. Finally, the current situation and research gap in these areas are identified and suggestions are provided for topics that need further research in the future.

Characterisation and modelling the mechanics of cellulose nanofibril added polyethersulfone ultrafiltration membranes.

The performance of the membranes can be improved by adding the appropriate amount of nanomaterials to the polymeric membranes that can be used for water/wastewater treatment. In this study, the effects of polyvinylpyrrolidone (PVP), the impact of different amounts (0.5% and 1% wt.) of cellulose nanofibril (CNF), and the combined effects of PVP-CNF on the properties/performance of the polyethersulfone-based (PES-based) membrane are investigated. All PES-based ultrafiltration (UF) membranes are manufactured employing the phase inversion method and characterised via Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and the relevant techniques to determine the properties, including porosity, mean pore size, contact angle, water content, and pure water flux tests. Furthermore, the thermal properties of the prepared membranes are investigated using thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) techniques. Experimental and numerical methods are applied for the mechanical characterisation of prepared membranes. For the experimental process, tensile tests under dry and wet conditions are conducted. The finite element (FE) method and Mori-Tanaka mean-field homogenisation are used as numerical methods to provide more detailed knowledge of membrane mechanics.

Characterisation and Mechanical Modelling of Polyacrylonitrile-Based Nanocomposite Membranes Reinforced with Silica Nanoparticles.

In this study, neat polyacrylonitrile (PAN) and fumed silica (FS)-doped PAN membranes (0.1, 0.5 and 1 wt% doped PAN/FS) are prepared using the phase inversion method and are characterised extensively. According to the Fourier Transform Infrared (FTIR) spectroscopy analysis, the addition of FS to the neat PAN membrane and the added amount changed the stresses in the membrane structure. The Scanning Electron Microscope (SEM) results show that the addition of FS increased the porosity of the membrane. The water content of all fabricated membranes varied between 50% and 88.8%, their porosity ranged between 62.1% and 90%, and the average pore size ranged between 20.1 and 21.8 nm. While the neat PAN membrane's pure water flux is 299.8 L/m2 h, it increased by 26% with the addition of 0.5 wt% FS. Furthermore, thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) techniques are used to investigate the membranes' thermal properties. Finally, the mechanical characterisation of manufactured membranes is performed experimentally with tensile testing under dry and wet conditions. To be able to provide further explanation to the explored mechanics of the membranes, numerical methods, namely the finite element method and Mori-Tanaka mean-field homogenisation are performed. The mechanical characterisation results show that FS reinforcement increases the membrane rigidity and wet membranes exhibit more compliant behaviour compared to dry membranes.

Effect of solid waste landfill leachate contaminants on hydraulic conductivity of landfill liners.

Landfilling is one of the most widely used methods to reduce the impact on the environment and human health by ensuring the management of solid wastes. For the process in question to be called landfill, the landfill leachate must be controlled and liner impermeability conditions must be provided. For this reason, compacted clay liners (CCL) and geosynthetic clay liners (GCL) with very low hydraulic conductivity are often used as hydraulic barriers in landfills to prevent the risk of leachate mixing with groundwater. However, as a result of various interactions between leachate-clay liners, changes occur in the hydraulic conductivity of the liners. In this review, the change (increase/decrease) in the hydraulic conductivity of the landfill liners caused by the contaminants in the leachate composition and the mechanisms responsible for this change were examined. In addition, deficiencies in the literature on this subject were identified and directions for future studies were presented.

Effects of Fe(OH)3 and MnO2 Flocs on Iron/Manganese Removal and Fouling in Aerated Submerged Membrane Systems.

Many treatment methods are used to remove iron and manganese from water. Aeration and membrane filtration are two of these methods. In this study, Fe2+ and Mn2+ removal by aeration with different catalysts and instead of simple membrane filtration applied in other studies, the aerated-submerged membrane systems were evaluated separately. When Fe(OH)3 was applied in the aeration step and complete oxidation of Fe2+ was obtained after 27 min, while complete Mn2+ oxidation was obtained in 76 min. However, when MnO2 was applied in the aeration step, complete oxidation of Fe2+ and Mn2+ was relatively slow (36 and 110 min, respectively). According to the results obtained from the aerated membrane system, Fe2+ and Mn2+ removal were extended by Fe(OH)3 via adsorption/surface oxidation. It is clearly shown from the flux, resistance results, scanning electron microscope (SEM) and Fourier transform infrared (FT/IR) spectroscopy observation that manganese oxides were deposited mainly in membrane pores forming membrane fouling by small flocs, while iron oxide particles were deposited on the membrane surface. Although the flux performance of PT PES membrane was higher than HF PP membrane, fouling resistance of HF PP membrane was higher than PT PES.

Manufacturing and Characterisation of Polymeric Membranes for Water Treatment and Numerical Investigation of Mechanics of Nanocomposite Membranes.

In this study, polyethersulfone (PES) and polyvinylidene fluoride (PVDF) microfiltration membranes containing polyvinylpyrrolidone (PVP) with and without support layers of 130 and 150 µm thickness are manufactured using the phase inversion method and then experimentally characterised. For the characterisation of membranes, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and pore size analysis are performed, the contact angle and water content of membranes are measured and the tensile test is applied to membranes without support layers. Using the results obtained from the tensile tests, the mechanical properties of the halloysite nanotube (HNT) and nano-silicon dioxide (nano SiO2) reinforced nanocomposite membranes are approximately determined by the Mori-Tanaka homogenisation method without applying any further mechanical tests. Then, plain polymeric and PES and PVDF based nanocomposite membranes are modelled using the finite element method to determine the effect of the geometry of the membrane on the mechanical behaviour for fifteen different geometries. The modelled membranes compared in terms of three different criteria: equivalent stress (von Mises), displacement, and in-plane principal strain. Based on the data obtained from the characterisation part of the study and the numerical analysis, the membrane with the best performance is determined. The most appropriate shape and material for a membrane for water treatment is specified as a 1% HNT doped PVDF based elliptical membrane.